Liquid Crystal Composition

ABSTRACT

Disclosed is a liquid crystal composition characterized by containing 15% by mass or more of a compound having a terminal structure represented by the general formula (I) below. This liquid crystal composition has high dielectric constant anisotropy (ε) and low rotational viscosity (γ1), and is thus suitably used as a liquid crystal composition for IPS liquid crystal displays or low voltage-driven TN liquid crystal displays. (I) (In the above formula, Q represents a saturated or unsaturated alkyl group having 1-8 carbon atoms which may be substituted by a halogen atom.)

TECHNICAL FIELD

The present invention relates to a liquid crystal composition and particularly to a liquid crystal composition that has a high dielectric anisotropy (Δε) and a low rotational viscosity (γ₁) and is thus suitable for IPS liquid crystal displays or low voltage-driven TN liquid crystal displays.

BACKGROUND ART

There have been manufactured a large number of liquid crystal display elements utilizing optical (refractive index) anisotropy (Δn) and dielectric anisotropy (Δε) characteristic of liquid crystal compounds. The liquid crystal display elements have been widely applied to clocks, calculators, various measuring instruments, automotive panels, word processors, electronic notebooks, portable phones, printers, computers, TV sets, and the like, with demand increasing year by year. A liquid crystal compound exhibits a characteristic liquid crystal phase between a solid phase and a liquid phase. The liquid crystal phase is roughly classified into nematic phase, smectic phase, and cholesteric phase, of which nematic phase is currently most widely used for display elements. Regarding to techniques applied to liquid crystal displays, as a display mode, there have been a large number of proposals, and currently known modes include, for example, dynamic scattering (DS), guest-host (GH), twist nematic (TN), super twist nematic (STN), thin film transistor (TFT), ferroelectric liquid crystal (FLC), and the like, while as a driving system, there are known static driving, time-division driving, active matrix driving, dual-frequency driving, and the like.

In common liquid crystal displays such as TN and STN, which have been conventionally widely used, the electric field generated for reorientation is substantially perpendicular to the liquid crystal layer. In contrast, in in-plane switching (IPS) mode, the electric field has a significant component parallel to the liquid crystal layer.

In IPS liquid crystal displays, by applying the electric field generated using comb electrodes on one substrate, liquid crystal molecules constituting a liquid crystal layer oriented almost parallel to the substrate surface are rotated within a plane almost parallel to the substrate, and the display function is based on the birefringence of the liquid crystal layer. Such displays are proposed, for example, in Patent Documents 1 to 5 and others.

IPS displays have advantages such as a wider viewing angle and a lower load capacity as compared with conventional TN displays resulting from the in-plane switching of liquid crystal molecules, thereby extending the application to monitor, television sets, and the like having larger display area.

A liquid crystal composition used for IPS liquid crystal displays is required to have a low rotational viscosity (γ₁) enabling fast response. Moreover, it is effective to increase the electrode spacing in order to increase the numerical aperture for improving the brightness of displays, but in such case the threshold voltage due to the structure of IPS cells increases. To suppress this drawback, liquid crystal compositions having a high dielectric anisotropy (Δε) are needed.

However, with conventionally known liquid crystal media, no liquid crystal composition with satisfactory performances has been yet attained.

For example, Patent Documents 6 and 7 and others propose a liquid crystal composition comprising a trifluorobenzene derivative for IPS liquid crystal devices; however, this liquid crystal composition is still unsatisfactory.

Patent Document 8 proposes an active matrix liquid crystal display using a liquid crystal whose specific resistance is not more than 1×10¹⁴ O·cm and not less than 1×10⁹ O·cm; however, the liquid crystal display is still unsatisfactory.

Further, it is expected that the market of liquid crystal display elements will develop in the field of portable information terminals such as portable phones, in which performances such as low power consumption are demanded. In this field, low voltage-driven TN liquid crystal displays are applied, and a liquid crystal composition used here is required to have a high dielectric anisotropy (Δε) for decreasing the threshold voltage and a low rotational viscosity (γ₁) for increasing the response speed. Various liquid crystal compositions have been studied to meet such demands. No satisfactory composition, however, has been realized yet.

Patent Document 1: Japanese Patent Laid-Open Publication No. S56-91277 Patent Document 2: Japanese Patent Application Laid-Open No. H5-505247 Patent Document 3: Japanese Patent Laid-Open Publication No. H6-160878 Patent Document 4: Japanese Patent Laid-Open Publication No. H7-225388

Patent Document 5: Pamphlet of International Publication No. 2004/053582

Patent Document 6: Japanese Patent Laid-Open Publication No. H10-245559 Patent Document 7: Japanese Patent Laid-Open Publication No. H11-29771 Patent Document 8: Japanese Patent Laid-Open Publication No. H7-306417

DISCLOSURE OF THE INVENTION Problems to be Solved by the Invention

Accordingly, an object of the present invention is to provide a liquid crystal composition that is useful for IPS liquid crystal displays and low voltage-driven TN liquid crystal displays and has a high dielectric anisotropy (Δε) and a low rotational viscosity (γ₁).

Means to Solve the Problems

As a result of the earnest studies, the present inventors have found that the above object can be achieved with a liquid crystal composition obtained using a specific liquid crystal compound.

The present invention has been accomplished based on the above findings and provides a liquid crystal composition comprising 15% by mass or more of a compound having a terminal structure represented by general formula (I) below.

(In the formula, Q represents an optionally halogenated C₁₋₈ saturated or unsaturated alkyl group.)

BEST MODE FOR CARRYING OUT THE INVENTION

Hereinafter, the liquid crystal composition of the present invention will be detailed with the preferable embodiments.

The liquid crystal composition of the present invention comprises 15% by mass or more of a compound having a terminal structure represented by general formula (I). The use of 15% by mass or more of the compound provides a liquid crystal composition having a high dielectric anisotropy (Δε) and a low rotational viscosity (γ₁). The content of the compound is preferably 20% by mass or more, particularly preferably 25% by mass or more, and the upper limit is preferably 80% by mass.

In general formula (I), the optionally halogenated C₁₋₈ saturated or unsaturated alkyl group represented by Q includes, for example, methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, hexyl, heptyl, octyl, isooctyl, 2-ethylhexyl, vinyl, allyl, monofluoromethyl, difluoromethyl, trifluoromethyl, 2,2,2-trifluoroethyl, 1,2,2-trifluoroethyl, 1,2,2-trifluorovinyl, perfluoroallyl, and the like.

Among the compounds containing a terminal structure represented by general formula (I), preferably used are compounds in which Q is perfluoroallyl, that is, compounds in which —O-Q in general formula (I) is represented by partial structural formula (II) below, because the resultant composition exists in nematic phase in a broad temperature range and has a low viscosity.

[Formula 2]

—O—CF₂—CF═CF₂  (II)

The compound having a terminal structure represented by general formula (I) includes, for example, the following compounds. In the following formulae R¹ and R² represent the same meanings as those in general formulae (III) and (IV) described later. Compounds shown in [Formula 3] to [Formula 7] and [Formula 11] to [Formula 15] are the compounds in which —O-Q in general formula (I) is represented by partial structural formula (II).

The liquid crystal composition of the present invention preferably contains at least one compound represented by general formula (III) below (component A) for increasing the specific resistance and preventing photo- or thermal degradation.

(In the formula, R₁ represents R₀, R₀O, R₀OCO, or R₀COO; R₀ represents an alkyl group, in which (an) unsaturated bond(s) may be contained, the —CH₂— group(s) may be replaced by —O—, —CO—, or —COO—, and part or all of the hydrogen atoms may be replaced by a halogen atom or cyano group;

A₁ is 1,4-phenylene [wherein the —CH═ group(s) may be replaced by —N═ and the hydrogen atom(s) may be replaced by a halogen atom or cyano group], 1,4-cyclohexylene [wherein the —CH₂— group(s) may be replaced by —O— or —S— and the hydrogen atom(s) may be replaced by a halogen atom or cyano group], or 2,6-naphthylene;

Z₁ is a single bond, —CH₂CH₂—, —CH═CH—, —(CH₂)₄—, —C═C—, or —CF₂CF₂—;

X₁ and X₂ each independently represent a hydrogen or fluorine atom;

Q₁ represents a halogen atom, haloalkyl group, haloalkoxy group, haloalkenyl group, or haloalkenyloxy group;

n is a number of 1 to 3; and when n is 2 or 3, a plurality of A₁ may be different and a plurality of Z₁ may be different.)

Some compounds represented by general formula (III) (component A) are included in the compounds having a terminal structure represented by general formula (I). Compound in which X₁ and X₂ are fluorine atoms and Q₁ is a C₁₋₈ haloalkoxy or haloalkenyloxy group in general formula (III) are included in the compounds having a terminal structure represented by general formula (I). Such compounds are preferably used as the compounds having a terminal structure represented by general formula (I).

In the liquid crystal composition of the present invention, the content of component A is preferably 50% to 99% by mass including the component included in the compounds having a terminal structure represented by general formula (I) and it is preferably 35 to 85% by mass excluding the component included in the compounds having a terminal structure represented by general formula (I).

Among the compounds represented by general formula (III), preferable are compounds represented by any of general formulae (III-1) to (III-3) below.

(In the formulae, R₁, X₁, X₂, and Q₁ represent the same as defined in general formula (III). X₅ to X₈ each independently represent a hydrogen or fluorine atom.)

R₁ in general formula (III) is preferably an alkyl or alkenyl group. It is particularly preferred to use a compound in which R₁ is an alkyl group and a compound in which R₁ is an alkenyl group together as the component A.

When the liquid crystal composition of the present invention further contains at least one compound represented by general formula (IV) below (component B), a more positive dielectric anisotropy (Δε) and a lower rotational viscosity (γ₁) can be attained.

(In the formula, R₂ represents R₀, R₀O, R₀OCO, or R₀COO; R₀ represents the same meaning as defined in general formula (III);

A₂ is 1,4-phenylene [wherein the —CH═ group(s) may be replaced by —N═ and the hydrogen atom(s) may be replaced by a halogen atom or cyano group], 1,4-cyclohexylene [wherein the —CH₂— group(s) may be replaced by —O— or —S— and the hydrogen atom(s) may be replaced by a halogen atom or cyano group], or 2,6-naphthylene;

Z₂ is —COO—, —OCO—, —CH₂O—, —OCH₂—, —(CH₂)₃O—, —O(CH₂)₃—, —CH═CHCH₂O—, —OCH₂CH═CH—, —CF₂O—, —OCF₂—, —CH₂CH₂—COO—, or —OCO—CH₂CH₂—;

X₃ and X₄ each independently represent a hydrogen or fluorine atom;

Q₂ represents a halogen atom, haloalkyl group, haloalkoxy group, haloalkenyl group, or haloalkenyloxy group;

m is a number of 1 to 3; and when m is 2 or 3, a plurality of A₂ may be different and a plurality of Z₂ may be different.)

Some compounds represented by general formula (IV) (component B) are included in the compounds having a terminal structure represented by general formula (I). Compound in which X₃ and X₄ are fluorine atoms and Q₂ is a C₁₋₈ haloalkoxy or haloalkenyloxy group in general formula (IV) are included in the compounds having a terminal structure represented by general formula (I). Such compounds are preferably used as the compounds having a terminal structure represented by general formula (I).

In the liquid crystal composition of the present invention, the content of component B is preferably 1 to 50% by mass including the component included in the compounds having a terminal structure represented by general formula (I), and it is preferably 0 to 50% by mass excluding the component included in the compounds having a terminal structure represented by general formula (I).

Among the compounds represented by general formula (IV), preferable are compounds represented by any of general formulae (IV-1) to (IV-3) below.

(In the formulae, R₂, X₃, X₄, and Q₂ represent the same meaning as those in general formula (IV). X₉ and X₁₀ each independently represent a hydrogen or fluorine atom.)

R₁ in general formula (III) and R₂ in general formula (IV) are R₀, R₀O, R₀OCO, or R₀COO, and R₀ represents an alkyl group. The alkyl group represented by R₀ includes, for example, methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, vinyl, allyl, butenyl, ethynyl, propynyl, butynyl, methoxymethyl, ethoxymethyl, propoxymethyl, butoxymethyl, methoxyethyl, ethoxyethyl, perfluoromethyl, perfluoroethyl, perfluoropropyl, monofluoromethyl, difluoromethyl, 2,2,2-trifluoroethyl, perfluorovinyl, perfluoroallyl, isopropyl, 1-methylpropyl, 2-methylpropyl, 2-butylmethyl, 3-methylbutyl, 2-methylpentyl, 3-methylpentyl, 2-ethylhexyl, 2-propylpentyl, 1-methylpentyl, and the like. Among these, C₁₋₈ groups are preferred.

A₁ in general formula (III) and A₂ in general formula (IV) are 1,4-phenylene [wherein the —CH═ group(s) may be replaced by —N═ and the hydrogen atom(s) may be replaced by a halogen atom or cyano group], 1,4-cyclohexylene [wherein the —CH₂— group(s) may be replaced by —O— or —S— and the hydrogen atom(s) may be replaced by a halogen atom or cyano group], or 2,6-naphthylene, specifically including cyclic groups exemplified below.

In general formulae (III) and (IV), the haloalkyl group represented by Q₁ or Q₂ includes monofluoromethyl, difluoromethyl, trifluoromethyl, 2-monofluoroethyl, 2,2,2-trifluoroethyl, perfluoroethyl, perfluoropropyl, perfluorobutyl, and the like; the haloalkoxy group includes those derived from these haloalkyl groups; the haloalkenyl group includes perfluoroallyl, perfluoro-1-propenyl, 1,1-difluoroallyl, perfluoro-3-butenyl, perfluoro-4-pentenyl, and the like; and the haloalkenyloxy group includes those derived from these haloalkenyl groups. Among these, C₁₋₃ groups are preferred.

Specific examples of the compound represented by general formula (III) include the compounds listed in [Formula 3] to [Formula 10] above and also include the following compounds, although not limited thereto. In the following compounds, R₁ is the same as defined in general formula (III).

Specific examples of the compound represented by general formula (IV) include the compounds exemplified in [Formula 11] to [Formula 16] above and also include the following compounds, although not limited thereto. In the following compounds, R₂ is the same as defined in general formula (IV).

In the liquid crystal composition of the present invention, the sum of component A and component B is preferably 100% by mass.

The liquid crystal composition of the present invention may contain a known liquid crystal compound or liquid crystal analogue. Such liquid crystal compounds or liquid crystal analogues include, for example, compounds represented by general formula (V) in [Formula 37] below [except compounds having a terminal structure represented by general formula (I) and compounds represented by general formula (III) or (IV)].

(In the formula, R represents a hydrogen atom or C₁₋₈ alkyl, alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, alkoxyalkyl, alkanoyloxy, or alkoxycarbonyl group optionally substituted with a halogen atom, cyano group, or the like; Y₂ represents a cyano group, halogen atom, or group represented by R; Y₁, Y₃, and Y₄ each represent a hydrogen atom, halogen atom, or cyano group; Z₃ and Z₄ each independently represent a direct bond, —CO—O—, —O—CO—, —CH₂O—, —OCH₂—, —CH₂CH₂—, —CH═CHCH₂O, —CF₂O—, —OCF₂—, or —C═C—, p represents 0, 1, or 2; and rings A₅, A₆, and A₇ each independently represent a benzene, cyclohexane, cyclohexene, pyrimidine, or dioxane ring.)

Accordingly, specific examples of compound represented by general formula (V) include compounds represented by [Formula 38] and [Formula 39] below. In these compounds, R, Y₁, Y₂, Y₃, and Y₄ represent the same meanings as those in general formula (V).

Among these liquid crystal compounds or liquid crystal analogues, the compounds exemplified below are components that can increase the dielectric anisotropy (Δε) without increasing the rotational viscosity (γ₁).

(In the formulae, R₀₀ represents an alkyl, alkenyl, alkoxy, or alkenyloxy group.)

Among these liquid crystal compounds or liquid crystal analogues, such compounds as exemplified below, that is, non-polar components, can improve the electro-optical properties, reliability, and the like.

The liquid crystal composition of the present invention may also contain a known chiral agent. The chiral agent includes, for example, the following compounds.

(In the formulae, R₆ and R₇ each independently represent an alkyl, alkoxy, alkylcarbonylalkoxy, or alkoxycarbonyl group, which may be interrupted by an ether linkage, may be substituted with a halogen atom and/or cyano group, and may contain an unsaturated bond; A₈, A₉, and A₁₀ each independently represent 1,4-phenylene, trans-1,4-cyclohexanediyl, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, or 1,4-cyclohexenylene, and these rings may be substituted with a halogen atom and/or cyano group; Z₅ and Z₆ each independently represent —COO—, —OCO—, —CH₂CH₂—, —CH═CH—, —(CH₂)₄—, —CH₂O—, —OCH₂—, —(CH₂)₃O—, —O(CH₂)₃—, —CH═CHCH₂O—, —OCH₂CH═CH—, —C═C—, —CF₂O—, —OCF₂—, —CFHCFH—, or a single bond; and q represents 0, 1, or 2, provided that at least one or more asymmetric carbon atoms are present.)

(In the formula, R₈ represents a hydrogen atom, halogen atom, alkyl, alkoxy, alkylcarbonyloxy, or alkoxycarbonyl group, optionally substituted aryl, aryloxy, arylcarbonyloxy, or aryloxycarbonyl group, or the like, and in these groups, the hydrogen atom(s) may be replaced by a halogen atom, and the ethylene group(s) may be replaced by an ethenylene or ethynylene group. R₉ represents an alkyl or alkenyl group. B₁ represents a condensed ring having only one double bond without sharing it with another ring, and the condensed ring may be substituted with an alkyl and/or alkoxy group.)

Specific examples of the chiral agent include the following compounds.

There may be also used, for example, chiral agents proposed in Japanese Patent Laid-Open Publication No. S63-175095, Japanese Patent Laid-Open Publication No. H1-242542, Japanese Patent Laid-Open Publication No. H1-258635, Japanese Patent Laid-Open Publication No. H6-200251, Japanese Patent Laid-Open Publication No. 2002-308833, and the like.

These chiral agents may be used alone or in combination of two or more. In this case, there may be used a combination of chiral agents different in helical twist direction or a combination of chiral agents with the same twist direction. Furthermore, for example, as proposed in Japanese Patent Laid-Open Publication No. H7-258641, there may be combined a chiral agent with positive temperature dependence of the rotatory power in its cholesteric phase and a chiral agent with negative temperature dependence of the rotatory power in its cholesteric phase.

The pitch may be adjusted in a range of 0.2μ to 300μ by changing the chiral agent and its concentration.

For attaining excellent long-term stability to light and heat, the liquid crystal composition of the present invention may contain an ultraviolet absorber such as benzotriazole-type, benzophenone-type, triazine-type, benzoate-type, oxanilide-type, and cyanoacrylate-type ultraviolet absorbers; a hindered amine light stabilizer; an antioxidant such as phenol-type, phosphorus-containing, and sulfur-containing antioxidants; and the like.

The liquid crystal composition of the present invention may contain a surfactant or the like for attaining antistatic effect. Such surfactants include, for example, compounds proposed in Japanese Patent Laid-Open Publication No. S59-4676, Japanese Patent Laid-Open Publication No. H4-36384, Japanese Patent Laid-Open Publication No. H4-180993, Japanese Patent Laid-Open Publication No. H11-212070, Japanese Patent Laid-Open Publication No. H8-337779, Japanese Patent Laid-Open Publication No. H9-67577, Japanese Patent Laid-Open Publication No. 2003-342580, and the like.

The liquid crystal composition of the present invention may be enclosed in a liquid crystal cell to configure various electro-optic display elements. To such electro-optic display elements, there may be applied various types of display modes, for example, dynamic scattering (DS), guest-host (GH), twist nematic (TN), super twist nematic (STN), thin film transistor (TFT), thin film diode (TFD), ferroelectric liquid crystal (FLC), antiferroelectric liquid crystal (AFLC), polymer dispersion liquid crystal (PD), vertical alignment (VA), in-plane switching (IPS), cholesteric-nematic phase transfer-type, and the like; and there may be applied various driving systems such as static driving, time-division driving, active matrix driving, and dual-frequency driving.

Since the liquid crystal composition of the present invention has a high dielectric anisotropy (Δε) and a low rotational viscosity (γ₁), electro-optic display elements obtained using the liquid crystal composition of the present invention are suitably used for IPS liquid crystal displays and low voltage-driven TN liquid crystal displays driven at a low voltage of 4 V or less (for example, 3.3 V or 2.5 V).

Such electro-optic display elements obtained using the liquid crystal composition of the present invention can be used for liquid crystal displays used in clocks, calculators, measuring instruments, automotive meters, copiers, cameras, OA equipment, portable personal computers, portable phones, and the like. Such electro-optic display elements can be also used for other applications, for example, photochromic windows, light-shielding shutters, polarization converters, and the like. Particularly, based on the characteristics, these elements are suitably used for liquid crystal displays used in monitors having large display area, wide-screen televisions, and portable information terminals such as PDA, portable personal computers and portable phones.

EXAMPLES

Hereafter, the present invention will be further detailed with Examples and the like. However, the present invention is not limited by Examples and the like below.

The following abbreviations are used in Examples and the like below.

CY: 1,4-cyclohexylene

PH: 1,4-phenylene

PHnF: n-fluoro-1,4-phenylene (If n is not described, it represents 4-fluoro.)

Dio: 1,3-dioxane-5,2-diyl

Pym: pyrimidine-5,2-diyl

Pyd: pyridazine-3,6-diyl

CE: 4,1-cyclohexenylene

Cn: Linear alkyl having n carbon atoms

Example 1

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 30.4 C4-CY—PH—OCF₂CF═CF₂ 5.7 C2-CY—CY—PH3F—OCF₂CF═CF₂ 10.45 C3-CY—CY—PH3F—OCF₂CF═CF₂ 12.35 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 16.15 C4-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 3.8 C5-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 7.6 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 8.55 C3-CY—PH—COO—PH3,5-diF—OCF₂CF═CF₂ 5

Example 2

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 9.5 C4-CY—PH—OCF₂CF═CF₂ 4.75 C3-CY—PH3F—OCF₂CF═CF₂ 14.25 C5-CY—PH3F—OCF₂CF═CF₂ 7.6 C2-CY—CY—PH3F—OCF₂CF═CF₂ 12.35 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 16.15 C4-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 7.6 C5-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 17.1 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 5.7 C3-CY—CY—COO—PH—F 5

Example 3

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 9.5 C4-CY—PH—OCF₂CF═CF₂ 4.75 C3-CY—PH3F—OCF₂CF═CF₂ 14.25 C5-CY—PH3F—OCF₂CF═CF₂ 7.6 C2-CY—CY—PH3F—OCF₂CF═CF₂ 12.35 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 16.15 C4-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 7.6 C5-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 17.1 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 5.7 C3-CY—CY—COO—PH3,5-diF—OCF₂CF═CF₂ 5

Example 4

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 21 C4-CY—PH—OCF₂CF═CF₂ 5 C5-CY—PH3F—OCF₂CF═CF₂ 5 C2-CY—CY—PH3F—OCF₂CF═CF₂ 9 C3-CY—CY—PH3F—OCF₂CF═CF₂ 12 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 11 C4-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 5 C5-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 10 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 14 C5-CY—COO—PH—F 8

Comparative Example 1

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C2-CY—CY—PH3,4-diF 15 C3-CY—CY—PH3,4-diF 17 C4-CY—CY—PH3,4-diF 15 C5-CY—CY—PH3,4-diF 12 C3-CY—PH—PH3,4-diF 4 C4-CY—PH—PH3,4-diF 3 C5-CY—PH—PH3,4-diF 6 C7-CY—PH—F 13 C2-CY—CY—PH3,4,5-triF 5 C2-CY—CY—PH3,5-diF—OCF₂H 4 C3-CY—PH—PH3,4,5-triF 6

The characteristic values of liquid crystal compositions obtained in Examples 1 to 4 and Comparative Example 1 are shown in [Table 1] below.

TABLE 1 Comparative Examples Example 1 2 3 4 1 NI Point 86.8 89.9 90.3 80.0 81.0 η 14 16 16 14 24 γ₁ 100 113 111 97 133 Δn 0.0908 0.0877 0.0887 0.0902 0.0873 Δe 5.2 5.1 5.4 4.8 5.3 Low-Temperature −30 −30 −30 −30 −20 Storage Stability NI Point: Nematic-isotropic phase transfer temperature, unit: ° C. η: Viscosity (20° C.), unit: mPa · s γ₁: Rotational viscosity coefficient (20° C.), unit: mPa · s Δn: Refractive index anisotropy (25° C., 589 nm) Δe: Dielectric anisotropy (25° C., 1 kHz) Low-Temperature Storage Stability: The lowest temperature at which no change was observed in a screw tube for two weeks. Unit: ° C.

Example 5

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-PH—PH3F—OCF₂CF═CF₂ 7 C3-CY—PH—OCF₂CF═CF₂ 16 C3-CY—PH3F—OCF₂CF═CF₂ 3 C2-CY—CY—PH3F—OCF₂CF═CF₂ 9 C3-CY—CY—PH3F—OCF₂CF═CF₂ 18 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 6 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 16 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 5 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 10 CH₂═CH—CY—PH—OCF₂CF═CF₂ 10

Example 6

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-PH—PH3F—OCF₂CF═CF₂ 10 C3-CY—PH—OCF₂CF═CF₂ 10 C4-CY—PH—OCF₂CF═CF₂ 5 C3-CY—PH3F—OCF₂CF═CF₂ 8 C5-CY—PH3F—OCF₂CF═CF₂ 4 C2-CY—CY—PH3F—OCF₂CF═CF₂ 12 C3-CY—CY—PH3F—OCF₂CF═CF₂ 15 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 8 C4-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 4 C5-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 6 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 18

Example 7

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-PH—PH3F—OCF₂CF═CF₂ 8 C3-CY—PH—OCF₂CF═CF₂ 20 C2-CY—CY—PH3F—OCF₂CF═CF₂ 6 C3-CY—CY—PH3F—OCF₂CF═CF₂ 16 C2-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 11 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 14 C3-CY—CY—PH—PH3,5-diF—OCF₂CF═CF₂ 6 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 8 CH₂═CH—CY—PH—OCF₂CF═CF₂ 11

Comparative Example 2

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C2-CY—CY—PH3,4-diF 13 C3-CY—CY—PH3,4-diF 14 C4-CY—CY—PH3,4-diF 12 C5-CY—CY—PH3,4-diF 10 C3-CY—PH—PH3,4-diF 9 C4-CY—PH—PH3,4-diF 6 C5-CY—PH—PH3,4-diF 13 C7-CY—PH—F 4 C2-CY—CY—PH3,5-diF—OCF₂H 3 C3-CY—PH—PH3,4,5-triF 2 C2-PH—C≡C—PH3,4-diF 2 C5-CY—PH—C1 7 C3-CY—PH—OCH3 5

The characteristic values of liquid crystal compositions obtained in Examples 5 to 7 and Comparative Example 2 are shown in [Table 2] below.

TABLE 2 Comparative Examples Example 5 6 7 2 NI Point 79.8 81.3 82.5 79.5 η 15 16 14 21 γ₁ 93 95 93 119 Δn 0.1005 0.1007 0.1019 0.0991 Δe 5.1 5.2 4.8 4.8 Low-Temperature −30 −30 −30 −20 Storage Stability NI Point: Nematic-isotropic phase transfer temperature, unit: ° C. η: Viscosity (20° C.), unit: mPa · s γ₁: Rotational viscosity coefficient (20° C.), unit: mPa · s Δn: Refractive index anisotropy (25° C., 589 nm) Δe: Dielectric anisotropy (25° C., 1 kHz) Low Temperature Storage Stability: The lowest temperature at which no change was observed in a screw tube for two weeks. Unit: ° C.

Example 8

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 31 C3-CY—PH3F—OCF₂CF═CF₂ 2 C3-CY—CY—PH3F—OCF₂CF═CF₂ 3 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 18 C4-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 4 C5-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 7 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 15 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 5 C3-CY—PH3,5-diF—CF₂O—PH3,5-diF—OCF₂CF═CF₂ 15

Example 9

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 18 C3-CY—PH3F—OCF₂CF═CF₂ 17 C2-CY—CY—PH3F—OCF₂CF═CF₂ 6 C3-CY—CY—PH3F—OCF₂CF═CF₂ 6 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 8 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 15 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 10 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 10 C3-CY—PH3,5-diF—CF₂O-PH3,5-diF—OCF₂CF═CF₂ 10

Example 10

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 13 C3-CY—PH3F—OCF₂CF═CF₂ 12 C2-CY—CY—PH3F—OCF₂CF═CF₂ 12 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 10 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 10 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 10 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 11 C3-CY—PH3,5-diF—COO—PH3,5-diF—OCF₂CF═CF₂ 10 CH₂═CH—CY—PH—OCF₂CF═CF₂ 12

Example 11

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 31 C3-CY—PH3F—OCF₂CF═CF₂ 5 C3-CY—CY—PH3F—OCF₂CF═CF₂ 16 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 6 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 18 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 10 C3-CY—PH3,5-diF—COO—PH3,5-diF—OCF₂CF═CF₂ 5 C3-PH—PH3,5-diF—CF₂O—PH3,5-diF—OCF₂CF═CF₂ 9

Example 12

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C3-CY—PH—OCF₂CF═CF₂ 30 C3-CY—PH3F—OCF₂CF═CF₂ 6 C3-CY—CY—PH3F—OCF₂CF═CF₂ 18 C3-PH—PH3F—PH3,5-diF—OCF₂CF═CF₂ 5 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 17 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 13 C3-CY—PH3,5-diF—COO—PH3,5-diF—OCF₂CF═CF₂ 3 C3-PH—PH3,5-diF—CF₂O—PH3,5-diF—OCF₂CF═CF₂ 8

Comparative Example 3

A liquid crystal composition was prepared as the following blend.

parts [blend] by mass C2-CY—CY—PH3,4-diF 8 C3-CY—CY—PH3,4-diF 12 C4-CY—CY—PH3,4-diF 10 C5-CY—CY—PH3,4-diF 8 C3-CY—PH—PH3,4-diF 7 C4-CY—PH—PH3,4-diF 5 C5-CY—PH—PH3,4-diF 10 C2-CY—CY—PH3,5-diF—OCF₂H 8 C2-CY-Dio-PH3,4,5-triF 10 C2-CY—PH—PH3,4,5-triF 9 C3-CY—PH—PH3,4,5-triF 6 C2-PH—C≡C—PH3,4-diF 2 C3-CY—PH—OCH₃ 5

The characteristic values of liquid crystal compositions obtained in Examples 8 to 12 and Comparative Example 3 are shown in [Table 3] below.

TABLE 3 Comparative Examples Example 8 9 10 11 12 3 NI Point 73.5 71.3 70.2 70.6 72.8 78.0 γ₁ 101 96 90 91 89 169 Δn 0.0941 0.0960 0.0942 0.0971 0.1008 0.1062 Δe 6.7 6.6 6.5 6.9 7.0 6.6 Low-Temperature −30 −30 −30 −20 −30 −10 Storage Stability NI Point: Nematic-isotropic phase transfer temperature, unit: ° C. γ₁: Rotational viscosity coefficient (20° C.), unit: mPa· s Δn: Refractive index anisotropy (25° C., 589 nm) Δe: Dielectric anisotropy (25° C., 1 kHz) Low-Temperature Storage Stability: The lowest temperature at which no change was observed in a screw tube for two weeks. Unit: ° C.

As clearly shown in Examples above, the liquid crystal composition of the present invention has both a high dielectric anisotropy (Δε) and a low rotational viscosity (γ₁), and further is excellent in low-temperature characteristics.

Composition Examples

Hereafter are shown other preferable examples of compositions as the liquid crystal composition of the present invention.

TABLE 4 parts liquid crystal compound by mass CH₂═CH—CY—CY—C5 15 C3-CY—CY—PH—C2 10 C2-CY—CY—PH3,5-diF—OCF₂H 12 C2-CY—CY—PH3,5-diF—OCF₃ 8 CH₂═CH—CY—CY—PH3,4-diF 13 C2-CY—PH3F—PH3,4,5-triF 4 C2-CY—CY—PH3,4-diF 5 C3-CY—CY—PH3,4,5-triF 6 C3-CY—CY—PH—OCF₃ 3 C3-CY—PH—PH3,4,5-triF 8 CH₂═CH—CY—CY—PH—C1 10 C3-CY—PH—OC2 6 100

TABLE 5 parts liquid crystal compound by mass C3-CY—PH—OC2 4 C3-CE-CY—C3 4 C3-CY—CY—C5 11 C3-CY—PH3,5-diF—OCF₃ 10 C2-CY—CY—PH3F—OCF₃ 5 C2-CY—CY—PH3,5-diF—OCF₂H 8 C2-CY—CY—PH3,4-diF 13 C3-CY—CY—PH3,4-diF 12 C5-CY—PH—PH3,4-diF 7 C3-CY—PH3F—PH3,4,5-triF 5 C2-CY—CY—COO—PH3,4-diF 6 C3-CY—PH3F—COO—PH—OCF₃ 3 C5-CY—CY—CH₂CH₂—PH2,3-diF—OCF₃ 3 C3-CY—CY—COO—PH3,5-diF—OCF₃ 5 C3-PH—PH—C≡C—PH2,6-diF—C3 4 100

TABLE 6 parts liquid crystal compound by mass CH₂═CH—CY—CY—C5 20 C7-CY—PH—F 5 C5-CY—PH—Cl 5 C2-CY—CY—PH3,5-diF—OCF₂H 8 C2-CY—CY—PH3,4-diF 11 CH₂═CH—CY—CY—PH3,4-diF 13 C3-CY-Dio-PH3,4-diF 15 C4-CY—PH—PH3,4-diF 8 C3-PH—PH3,5-diF—CF₂O—PH3,5-diF—OCF₃ 5 C2-CY—PH3F—COO—PH3,5-diF—OCF₂H 6 C3-CY—CY—PH3,5-diF—OCF₂CH═CH₂ 4 100

TABLE 7 parts liquid crystal compound by mass CH₂═CH—CY—CY—C5 20 C3-CY—PH—OC1 10 C3-CY—CY—C3 8 C2-CY—CY—PH3,5-diF—OCF₂H 10 CH₂═CH—CY—CY—PH3,4-diF 12 C3-CY—CY—PH3,4,5-triF 12 C3-CY—PH3F—PH3,4,5-triF 7 C3-CY—CY—COO—PH3,5-diF—OCF₃ 8 C3-CY—CY—COO—PH3,4-diF 6 C3-CY—PH3F—COO—PH—OCF₃ 7 100

TABLE 8 parts liquid crystal compound by mass C3-CY—PH—OC2 5 CH₂═CH—CY—PH—C3 18 CH₂═CH—CY—CY—PH—C1 8 C3-CY-Pyd-CY—C4 8 C3-CY—CY—PH—OCF₃ 7 C3-CY—CY—PH3,4-diF 15 C3-CY—CY—PH3,5-diF—OCF₂H 12 C2-CY—CY—COO—PH3,4-diF 5 C3-CY—PH3,5-diF—COO—PH3,5-diF—OCF₃ 7 C3-CY—CY—CF₂O—PH3,4,5-triF 9 C3-CY—CY—PH—C2 6 100

TABLE 9 parts liquid crystal compound by mass CH₂═CH—CY—PH3F—OCF₂CF═CF₂ 6 CH₂═CH—CY—CY—C5 10 C3-CY—CY—C5 5 C3-CY—PH—OCF₂CF═CF₂ 10 CH₂═CH—CY—CY—PH—C1 9 C2-CY—CY—PH3F—OCF₂CF═CF₂ 14 C3-CY—CY—PH3F—OCF₂CF═CF₂ 9 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 11 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 5 C3-CY—PH—PH3,5-diF—OCF₂CF═CF₂ 16 C3-CY—CY—PH3F—PH3,5-diF—OCF₂CF═CF₂ 5 100

TABLE 10 parts liquid crystal compound by mass C3-CY—CY—C5 16 C3-CY—PH3F—OCF₂CF═CF₂ 15 C3-CY—CY—PH3,5-diF—OCH₃ 4 C3-CY—PH—C≡C—PH3F—OCF₂CF═CF₂ 6 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 8 CH2═CH—CY—CY—PH3F—OCF₂CF═CF₂ 10 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 15 C3-CY—CY—COO—PH3,4-diF 10 C2-CY—PH3F—COO—PH3,4-diF 5 C3-CY—PH3F—COO—PH—OCF₃ 5 C2-CY—PH3F—PH3F—OCF═CFCF₃ 6 100

TABLE 11 parts liquid crystal compound by mass C3-CY—PH—OC2 8 C3-CY—CY—C5 5 CH₂═CH—CY—CY—C5 18 CH₂═CH—CY—CY—PH3F—OCF₂CF═CF₂ 12 C3-CY—CY—PH3,4,5-diF 10 C3-CY—CY—PH3,4-diF 12 C2-CY—PH3F—PH3,4,5-triF 6 C3-PH—PH3F—PH3,4,5-triF 6 C3-CY—PH3,5-diF—CF₂O—PH3,5-diF—OCF₂CF═CF₂ 12 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 6 C2-CY—PH3,5-diF—COO—PH3,5-diF—OCF₂CF═CF₂ 5 100

TABLE 12 parts liquid crystal compound by mass C3-PH—PH3F—OCF₂CF═CF₂ 8 C2-CY—PH—OCF₂CF═CF₂ 13 C3-CY—PH3F—OCF₂CF═CF₂ 5 C7-CY—PH—F 12 CH₂═CH—CY—CY—PH3,4-diF 18 C3-CY—CY—PH3,4-diF 9 C2-CY—PH3F—PH3,4,5-triF 11 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 12 C5-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 12 100

TABLE 13 parts liquid crystal compound by mass C3-CY—CY—CF₃ 5 C3-CY—CY—C5 7 C3-CY—PH3F—CN 6 C1-CH═CH—CY—PH—CN 10 C2-CY—CY—PH3,4-diF 12 C2-CY—CY—PH3,5-diF—OCF₂H 11 C3-CY—CY—PH3,4-diF 18 C3-CY—CY—PH3,4,5-triF 9 C3-CY—PH3F—COO—PH3,5-diF—OCF₃ 5 C3-PH—PH3,5-diF—CF₂O—PH3,5-diF—OCF₂H 4 C3-CY—CY—COO—PN—CN 5 C5-CY—CY—PH3F—OCF₃ 8 100

TABLE 14 parts liquid crystal compound by mass C3-CY—PH—CN 8 CH₂═CH—CY—CY—C5 22 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 12 C2-CY—CY—PH3F—OCF₂CF═CF₂ 12 C3-CY—CY—PH3,4-diF 14 C3-CY—CY—PH3,5-diF—OCF₂H 6 C3-CY—PH3F—PH3,4,5-triF 6 C3-PH—PH3,5-diF—CF₂O—PH3,5-diF—OCF₂CF═CF₂ 8 C3-CY—PH3F—COO—PH3,5-diF—OCF₂CF═CF₂ 5 C4-CY—PH3F—COO—PH—CN 7 100

TABLE 15 parts liquid crystal compound by mass C2-PH—COO—PH3F—CN 8 C3-CY—PH3F—OCF₂CF═CF₂ 15 CH₂═CH—CY—CY—C5 6 C3-CY—PH3,5-diF—CN 5 C2-CY—CY—PH3,4-diF 10 C3-CY—CY—PH3F—OCF₂CF═CF₂ 13 C3-CY—CY—PH3,5-diF—OCF₂CF═CF₂ 9 CH₂═CH—CY—CY—PH3,5-diF—OCF₂CF═CF₂ 9 CH₂═CH—CY—CY—PH—C1 12 C3-CY—CY—CY—PH—C2 8 C3-CY—CY—COO—PH—CY—C3 5 100

INDUSTRIAL APPLICABILITY

The liquid crystal composition of the present invention has a high dielectric anisotropy (Δε) and a low rotational viscosity (γ₁) and thus is suitably used as a liquid crystal composition for IPS liquid crystal displays or low voltage-driven TN liquid crystal displays. 

1. A liquid crystal composition comprising 15% by mass or more of a compound having a terminal structure represented by general formula (I) below:

wherein Q represents an optionally halogenated saturated or unsaturated alkyl group having 1 to 8 carbon atoms.
 2. The liquid crystal composition according to claim 1 comprising at least one compound in which —O-Q in general formula (I) is represented by partial structural formula (II) below: [Formula 2] —O—CF₂—CF═CF₂  (II)
 3. The liquid crystal composition according to claim 1 comprising at least one compound represented by general formula (III) below (Component A), with the proviso of excluding components included in the compounds having a terminal structure represented by general formula (I):

wherein R₁ represents R₀, R₀O, R₀OCO, or R₀COO; R₀ represents an alkyl group, in which (an) unsaturated bond(s) may be contained, the —CH₂— group(s) may be replaced by —O—, —CO—, or —COO—, and part or all of the hydrogen atoms may be replaced by a halogen atom or cyano group; A₁ is 1,4-phenylene in which the —CH═ group(s) may be replaced by —N═ and the hydrogen atom(s) may be replaced by a halogen atom or cyano group, 1,4-cyclohexylene in which the —CH₂— group(s) may be replaced by —O— or —S— and the hydrogen atom(s) may be replaced by a halogen atom or cyano group, or 2,6-naphthylene; Z₁ is a single bond, —CH₂CH₂—, —CH═CH—, —(CH₂)₄—, —C═C—, or —CF₂CF₂—; X₁ and X₂ each independently represent a hydrogen or fluorine atom; Q₁ represents a halogen atom, haloalkyl group, haloalkoxy group, haloalkenyl group, or haloalkenyloxy group; n is a number of 1 to 3; and when n is 2 or 3, a plurality of A₁ may be different and a plurality of Z₁ may be different.
 4. The liquid crystal composition according to claim 1, wherein the compound having a terminal structure represented by general formula (I) is at least one compound represented by general formula (III) (Component A), with the proviso of excluding components not included in the compounds having a terminal structure represented by general formula (I).
 5. The liquid crystal composition according to claim 1 comprising at least one compound represented by general formula (IV) below (Component B), with the proviso of excluding components included in the compounds having a terminal structure represented by general formula (I):

wherein, R₂ represents R₀, R₀O, R₀OCO, or R₀COO; R₀ represents the same meaning as that in general formula (III); A₂ is 1,4-phenylene in which the —CH═ group(s) may be replaced by —N═ and the hydrogen atom(s) may be replaced by a halogen atom or cyano group, 1,4-cyclohexylene in which the —CH₂— group(s) may be replaced by —O— or —S— and the hydrogen atom(s) may be replaced by a halogen atom or cyano group, or 2,6-naphthylene; Z₂ is —COO—, —OCO—, —CH₂O—, —OCH₂—, —(CH₂)₃O—, —O(CH₂)₃—, —CH═CHCH₂O—, —OCH₂CH═CH—, —CF₂O—, —OCF₂—, —CH₂CH₂—COO—, or —OCO═CH₂CH₂—; X₃ and X₄ each independently represent a hydrogen or fluorine atom; Q₂ represents a halogen atom, haloalkyl group, haloalkoxy group, haloalkenyl group, or haloalkenyloxy group; m is a number of 1 to 3; and when m is 2 or 3, a plurality of A₂ may be different and a plurality of Z₂ may be different.
 6. The liquid crystal composition according to claim 1, wherein the compound having a terminal structure represented by general formula (I) is at least one compound represented by general formula (IV) (Component B), with the proviso of excluding components not included in the compounds having a terminal structure represented by general formula (I).
 7. The liquid crystal composition according to claim 1, wherein Component A is at least one compound represented by any of general formulae (III-1) to (III-3) below:

wherein, R₁, X₁, X₂, and Q₁ represent the same meaning as those in general formula (III); and X₅ to X₈ each independently represent a hydrogen or fluorine atom.
 8. The liquid crystal composition according to claim 5, wherein Component B is at least one compound represented by any of general formulae (IV-1) to (IV-3) below:

wherein, R₂, X₃, X₄, and Q₂ represent the same meanings as those in general formula (IV); and X₉ and X₁₀ each independently represent a hydrogen or fluorine atom.
 9. The liquid crystal composition according to claim 3, wherein Components A are at least one or more compounds in which R₁ in general formula (III) is an alkyl group and at least one or more compounds in which R₁ in general formula (III) is an alkenyl group.
 10. The liquid crystal composition according to claim 3, wherein the sum of Component A and Component B is 100% by mass.
 11. The liquid crystal composition according to claim 1 used for IPS liquid crystal displays.
 12. The liquid crystal composition according to claim 1 used for low voltage-driven TN liquid crystal displays.
 13. The liquid crystal composition according to claim 2 comprising at least one compound represented by general formula (III) below (Component A), with the proviso of excluding components included in the compounds having a terminal structure represented by general formula (I):

wherein R₁ represents R₀, R₀O, R₀OCO, or R₀COO; R₀ represents an alkyl group, in which (an) unsaturated bond(s) may be contained, the —CH₂— group(s) may be replaced by —O—, —CO—, or —COO—, and part or all of the hydrogen atoms may be replaced by a halogen atom or cyano group; A₁ is 1,4-phenylene in which the —CH═ group(s) may be replaced by —N═ and the hydrogen atom(s) may be replaced by a halogen atom or cyano group, 1,4-cyclohexylene in which the —CH₂— group(s) may be replaced by —O— or —S— and the hydrogen atom(s) may be replaced by a halogen atom or cyano group, or 2,6-naphthylene; Z₁ is a single bond, —CH₂CH₂—, —CH═CH—, —(CH₂)₄—, —C≡C—, or —CF₂CF₂—; X₁ and X₂ each independently represent a hydrogen or fluorine atom; Q₁ represents a halogen atom, haloalkyl group, haloalkoxy group, haloalkenyl group, or haloalkenyloxy group; n is a number of 1 to 3; and when n is 2 or 3, a plurality of A₁ may be different and a plurality of Z₁ may be different.
 14. The liquid crystal composition according to claim 4, wherein Component A is at least one compound represented by any of general formulae (III-1) to (III-3) below:

wherein, R₁, X₁, X₂, and Q₁ represent the same meaning as those in general formula (III); and X₅ to X₈ each independently represent a hydrogen or fluorine atom.
 15. The liquid crystal composition according to claim 5, wherein Component A is at least one compound represented by any of general formulae (III-1) to (III-3) below:

wherein, R₁, X₁, X₂, and Q₁ represent the same meaning as those in general formula (III); and X₅ to X₈ each independently represent a hydrogen or fluorine atom.
 16. The liquid crystal composition according to claim 6, wherein Component A is at least one compound represented by any of general formulae (III-1) to (III-3) below:

wherein, R₁, X₁, X₂, and Q₁ represent the same meaning as those in general formula (III); and X₅ to X₈ each independently represent a hydrogen or fluorine atom.
 17. The liquid crystal composition according to claim 6 wherein Component B is at least one compound represented by any of general formulae (IV-1) to (IV-3) below:

wherein, R₂, X₃, X₄, and Q₂ represent the same meanings as those in general formula (IV); and X₉ and X₁₀ each independently represent a hydrogen or fluorine atom.
 18. The liquid crystal composition according to claim 7, wherein Component B is at least one compound represented by any of general formulae (IV-1) to (IV-3) below:

wherein, R₂, X₃, X₄, and Q₂ represent the same meanings as those in general formula (IV); and X₉ and X₁₀ each independently represent a hydrogen or fluorine atom. 